Microsoft Excel file 'Raw Data': 
Tab 1: Raw data obtained via differential scanning calorimetry (DSC) of the monomer BPLC and bulk cured and 3D printed polymer samples
Tab 2: Raw data obtained via dynamic mechanical analysis (DMA) of bulk cured and 3D printed polymer samples
Tab 3: Raw data obtained via tensile tests of bulk cured and 3D printed polymer samples
Tab 4: Raw data obtained via shape memory tests of a bulk cured polymer sample
Tab 5: Raw data obtained via FTIR-VIS-spectroscopy of 3D printed polymer samples
Compound descriptions in the files included herein adhere to the naming in the related publication referenced in the Related Works section, where all compounds are described in detail and drawn as structural formulas. In brief:
BPLC: 1,1′-[1,1′-Biphenyl]-4,4′-diyl di-10-undecenoate
CHTT: 1,2,4-cyclohexanetriethanethiol
All bulk-cured samples and 3D printed samples were cured from formulations consisting of equimolar reactive end groups of BPLC and CHTT. They were cured with 1 mol% (based on terminal double bonds) of photoinitiator (2,4,6-trimethylbenzoyl)-phosphine oxide (TPO). 0.2 wt% pyrogallol were utilized as inhibitor.
The “3D prints additional data” folder contains mesh files in STL format for all mono-material printed parts. For the multi-material parts where voxel-based models were used, the slices that were used to compound the printed parts are included in png format. 
Mesh Files: 
•	TensileTest
•	DMA
•	Chip
•	Pyramid

Voxel-based models:
•	5LayerTensileTest
•	QrCodeHidden
•	QrCodeRegular
•	ShapeMemoryCubeFaces
•	Skelett
•	WarningSign
•	TensileTestCrossSection
There is currently no known standard when it comes to multi-material models. Since we used a DLP light engine with a resolution of 1920 x 1080 pixel all images required for the light engine have to be in that format. In our voxel-based modelling environment models can be stored as a set of images, each image represents one printed layer. Each image is processed in the printing process as follows: If the original png image has colour information or a bit depth greater than 8, the image gets converted to a grayscale image with bit depth of 8 (which allows 28 possible values, ranging from black to white).  Each pixel is than interpreted:
•	Black pixel (value: 0): Nothing is printed
•	Gray pixel (value in range 1 – 254): Printed with the crystalline property
•	White pixel (value: 255):  Printed with the amorphous property
